2021-2022

142. Yin, Z.; Yu, J.; Xie, Z.; Yu, S.-W.; Zhang, L.; Akauola, T.; Chen, J. G.*; Huang, W.Y.*; Qi, L.*; Zhang, S.* Hybrid Catalyst Coupling Single-Atom Ni and Nanoscale Cu for Efficient CO2 Electroreduction to Ethylene. J. Am. Chem. Soc., 2022, 144, 20931-20938. DOI: 10.1021/jacs.2c09773

141. Zhao, T. Y.; Lapak, M. P.; Behera, R.; Zhao, H.; Ferrer, M.-J.; Weaver, H. E. H.; Huang, W.Y.; Bowers, C. R.*, Perpetual hyperpolarization of allyl acetate from parahydrogen and continuous flow heterogeneous hydrogenation with recycling of unreacted propargyl acetate. Journal of Magnetic Resonance Open, 2022, 12-13, 100076. DOI: 10.1016/j.jmro.2022.100076

140. Liu, H.; Agrawal, N.; Ganguly, A.; Chen, Y.; Lee, J.; Yu, J.; Huang, W.Y.; Mba Wright*, M.; Janik, M. J.*; Li, W.*, Ultra-low voltage bipolar hydrogen production from biomass-derived aldehydes and water in membrane-less electrolyzers. Energy & Environmental Science, 2022, 15 (10), 4175-4189. DOI: 10.1039/D2EE01427K

139. Yu, J.; Yu, S.-W.; Qi, Z.; Fang, X.; Kim, T.-H.; Zhou, L.; Zhang, S.*; Huang, W.Y.*, Synthesis of PtSn4 Intermetallic Nanodisks through a Galvanic Replacement Mechanism. Chem. Mater., 2022, 34 (15), 6968-6976. DOI: 10.1021/acs.chemmater.2c01381

138. Bhaskar, G.; Gvozdetskyi, V.; Carnahan, S. L.; Wang, R.; Mantravadi, A.; Wu, X.; Ribeiro, R. A.; Huang, W.Y.; Rossini, A. J.; Ho, K.-M.; Canfield, P. C.; Lebedev, O. I.; Zaikina, J. V.*, Path Less Traveled: A Contemporary Twist on Synthesis and Traditional Structure Solution of Metastable LiNi12B8. ACS Materials Au, 2022, 2, 614-625. DOI: 10.1021/acsmaterialsau.2c00033

137. Perras, F. A.*; Goh, T. W.; Huang, W.Y. t1-noise elimination by continuous chemical shift anisotropy refocusing. Solid State Nucl. Magn. Reson., 2022, 101807. DOI: 10.1016/j.ssnmr.2022.101807

136. Du, Y.; Behera, R. K.; Maligal-Ganesh, R. V.; Chen, M.; Zhao, T. Y.; Huang, W.Y.*; Bowers, C. R.* Mesoporous Silica Encapsulated Platinum–Tin Intermetallic Nanoparticles Catalyze Hydrogenation with an Unprecedented 20% Pairwise Selectivity for Parahydrogen Enhanced Nuclear Magnetic Resonance. J. Phys. Chem. Lett., 2022, 4125-4132. DOI: 10.1021/acs.jpclett.2c00581

135. Lin, Y.; Nie, R.; Li, Y.; Wu, X.; Yu, J.; Xie, S.; Shen, Y.; Mao, S.; Chen, Y.; Lu, D.; Bao, Z.; Yang, Q.; Ren, Q.; Yang, Y.; Liu, F.; Qi, L.*; Huang, W.Y.*; Zhang, Z.* Highly efficient and anti-poisoning single-atom cobalt catalyst for selective hydrogenation of nitroarenes. Nano Research, 2022, 15, 10006-10013. DOI: 10.1007/s12274-022-4294-6

134. Perras, F. A.*; Carnahan, S. L.; Lo, W.-S.; Ward, C. J.; Yu, J.; Huang, W.Y.; Rossini, A. J. Hybrid quantum-classical simulations of magic angle spinning dynamic nuclear polarization in very large spin systems. J. Chem. Phys., 2022, 156, 124112. DOI: 10.1063/5.0086530

133. Luo, Z.; Yin, Z.; Yu, J.; Yan, Y.; Hu, B.; Nie, R.; Kolln, A. F.; Wu, X.; Behera, R. K.; Chen, M.; Zhou, L.; Liu, F.; Wang, B.; Huang, W.Y.*; Zhang, S.*; Qi, L.* General Synthetic Strategy to Ordered Mesoporous Carbon Catalysts with Single-Atom Metal Sites for Electrochemical CO2 Reduction. Small, 2022, e2107799. DOI: 10.1002/smll.202107799

132. Lyu, X.; Wu, X.; Liu, Y.; Huang, W.Y.*; Lee, B.*; Li, T.* Synthesis and Characterization of Mesoporous Silica Nanoparticles Loaded with Pt Catalysts. Catalysts, 2022, 12, 183. DOI: 10.3390/catal12020183

131. Dai, L.; Shen, Y.; Chen, J. Z.; Zhou, L.; Wu, X.; Li, Z.; Wang, J.; Huang, W.Y.; Miller, J. T.; Wang, Q.; Cao, A.; Wu, Y.* MXene-Supported, Atomic-Layered Iridium Catalysts Created by Nanoparticle Re-Dispersion for Efficient Alkaline Hydrogen Evolution. Small, 2022, 2105226. DOI: 10.1002/smll.202105226

130. Wu, X.; Tennakoon, A.; Yappert, R.; Esveld, M.; Ferrandon, M. S.; Hackler, R. A.; LaPointe, A. M.; Heyden, A.; Delferro, M.; Peters, B.;* Sadow, A. D.;* Huang, W.Y.* Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins. J. Am. Chem. Soc., 2022, 144, 5323-5334. DOI: 10.1021/jacs.1c11694

129. Dorn, R. W.; Heintz, P. M.; Hung, I.; Chen, K.; Oh, J.-S.; Kim, T.-H.; Zhou, L.; Gan, Z.; Huang, W.Y.*; Rossini, A. J.* Atomic-Level Structure of Mesoporous Hexagonal Boron Nitride Determined by High-Resolution Solid-State Multinuclear Magnetic Resonance Spectroscopy and Density Functional Theory Calculations. Chem. Mater., 2022, 34, 1649-1665. DOI: 10.1021/acs.chemmater.1c03791

128. Hu, H.; Nie, Y.; Tao, Y.; Huang, W.Y.; Qi, L.*; Nie, R.* Metal-free carbocatalyst for room temperature acceptorless dehydrogenation of N-heterocycles. Sci. Adv., 2022, 8, eabl9478. DOI: 10.1126/sciadv.abl9478

127. Chen, M.; Gupta, G.; Ordonez, C. W.; Lamkins, A. R.; Ward, C. J.; Abolafia, C. A.; Zhang, B.; Roling, L. T.*; Huang, W.Y.* Intermetallic Nanocatalyst for Highly Active Heterogeneous Hydroformylation. J. Am. Chem. Soc., 2021, 143, 20907-20915. DOI: 10.1021/jacs.1c09665

126. Chen, M.; Bowers, C. R.*; Huang, W.Y.* Silica-Encapsulated Intermetallic Nanoparticles for Highly Active and Selective Heterogeneous Catalysis. Accounts of Materials Research, 2021, 2, 1190-1202. DOI: 10.1021/accountsmr.1c00153

125. Yu, J.; Kolln, A. F.; Jing, D.; Oh, J.; Liu, H.; Qi, Z.; Zhou, L.; Li, W.; Huang, W.Y.* Precisely Controlled Synthesis of Hybrid Intermetallic–Metal Nanoparticles for Nitrate Electroreduction. ACS Appl. Mater. Interfaces, 2021, 13, 52073-52081. DOI: 10.1021/acsami.1c09301

124. Lai, K. C.; Chen, M.; Yu, J.; Han, Y.; Huang, W.Y.; Evans, J. W.* Shape Stability of Truncated Octahedral fcc Metal Nanocrystals. ACS Appl. Mater. Interfaces, 2021, 13, 51954–51961. DOI: 10.1021/acsami.1c07894

123. Chen, M.; Yan, Y.; Gebre, M.; Ordonez, C.; Liu, F.; Qi, L.; Lamkins, A.; Jing, D.; Dolge, K.; Zhang, B.; Heintz, P.; Shoemaker, D. P.*; Wang, B.*; Huang, W.Y.* Thermal Unequilibrium of PdSn Intermetallic Nanocatalysts: From in situ Tailored Synthesis to Unexpected Hydrogenation Selectivity. Angew. Chem. Int. Ed., 2021, 60, 18309–18317. DOI: 10.1002/anie.202106515

122. Chen, J.; Qi, L.*; Zhang, B.; Chen, M.; Kobayashi, T.; Bao, Z.; Yang, Q.; Ren, Q.; Huang, W.Y.*; Zhang, Z.* Tandem synthesis of tetrahydroquinolines and identification of the reaction network by operando NMR. Catal. Sci. Technol., 2021, 11, 4332-4341. DOI: 10.1039/D1CY00418B

121. Zhang, B.; Li, X.; Chen, J.; Liu, T.; Cruz, A.; Pei, Y.; Chen, M.; Wu, X.; Huang, W.Y.* Tandem Synthesis of ϵ-Caprolactam from Cyclohexanone by an Acidified Metal-organic Framework. ChemCatChem, 2021, 13, 3084-3089. DOI: 10.1002/cctc.202100425

120. Zhang, Z.-Q.; Pei, Y.-C.; Xiao, M.-J.; Hu, G.; Huang, Z.-P.; Song, T.; Wang, Q.*; Huang, W.Y.*; Peng, Y.*; Zhang, H.-L.* In situ observation of the crystal structure transition of Pt–Sn intermetallic nanoparticles during deactivation and regeneration. Chem. Commun., 2021, 57, 5454-5457. DOI: 10.1039/D1CC01181B

119. Dong, B.*; Mansour, N.; Huang, T.-X.; Huang, W.Y.*; Fang, N.* Single molecule fluorescence imaging of nanoconfinement in porous materials. Chem. Soc. Rev., 2021, 50, 6483-6506. DOI: 10.1039/D0CS01568G

118. Mitran, G.*; Chen, S.; Huang, W.Y.; Seo, D.-K.* La-H-zeolites: efficient catalysts for acetic acid ketonic decarboxylation and esterification. J. Chem. Technol. Biotechnol., 2021, 96, 2022-2032. DOI: 10.1002/jctb.6732

117. Li, Y.*; Lo, W.-S.*; Zhang, F.*; Si, X.; Chou, L.-Y.; Liu, X.-Y.; Williams, B. P.; Li, Y.-H.; Jung, S.-H.; Hsu, Y.-S.; Liao, F.-S.; Shieh, F.-K.; Ismail, M. N.; Huang, W.Y.*; Tsung, C.-K.* Creating an Aligned Interface between Nanoparticles and MOFs by Concurrent Replacement of Capping Agents. J. Am. Chem. Soc., 2021, 143, 5182-5190. DOI: 10.1021/jacs.1c01357

116. Bhaskar, G.; Gvozdetskyi, V.; Batuk, M.; Wiaderek, K. M.; Sun, Y.; Wang, R.; Zhang, C.; Carnahan, S. L.; Wu, X.; Ribeiro, R. A.; Bud’ko, S. L.; Canfield, P. C.; Huang, W.Y.; Rossini, A. J.; Wang, C.-Z.; Ho, K.-M.; Hadermann, J.; Zaikina, J. V.* Topochemical Deintercalation of Li from Layered LiNiB: toward 2D MBene. J. Am. Chem. Soc., 2021, 143, 4213-4223. DOI: 10.1021/jacs.0c11397

115. Zhang, B.; Goh, T. W.; Kobayashi, T.*; Jing, D.; Wu, X.; Chen, M.; Huang, W.Y.* Structure evolution of single-site Pt in a metal–organic framework. J. Chem. Phys., 2021, 154, 094710. DOI: 10.1063/5.0041904

114. Lo, W.-S.; Chou, L.-Y.; Young, A. P.; Ren, C.; Goh, T. W.; Williams, B. P.; Li, Y.; Chen, S.-Y.; Ismail, M. N.; Huang, W.Y.; Tsung, C.-K.* Probing the Interface between Encapsulated Nanoparticles and Metal–Organic Frameworks for Catalytic Selectivity Control. Chem. Mater., 2021. DOI: 10.1021/acs.chemmater.0c03007

113. Mitran, G.*; Chen, S.; Dolge, K. L.; Huang, W.Y.; Seo, D.-K.* Ketonic decarboxylation and esterification of propionic acid over beta zeolites. Microporous Mesoporous Mater., 2021, 310, 110628. DOI: 10.1016/j.micromeso.2020.110628

112. Naik, P. J.; Chatterjee, P.; Chen, S.; Huang, W.Y.; Slowing, I. I.* Regulating the Catalytic Activity of Pd Nanoparticles by Confinement in Ordered Mesoporous Supports. ChemCatChem, 2021, 13, 539-542. DOI: 10.1002/cctc.202001594