Prior Publications (Postdoctoral / Ph.D.)
19. Liao, X.; Stanley, L. M.; Hartwig, J. F. “Enantioselective Total Syntheses of (−)-Taiwaniaquinone H and (−)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation” J. Am. Chem. Soc. 2010, 132, 8918-8920. DOI: 10.1021/ja110215b
18. Stanley, L. M.; Bai, C.; Ueda, M.; Hartwig, J. F. “Iridium-Catalyzed Kinetic Asymmetric Transformations of Racemic Allylic Benzoates” J. Am. Chem. Soc. 2010, 132, 8918-8920. DOI: 10.1021/ja103779e
17. Hartwig, J. F.; Stanley, L. M. “Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution” Acc. Chem. Res. 2010, 43, 1461-1475. DOI: 10.1021/ar100047x
16. Stanley, L. M.; Hartwig, J. F. “Iridium-Catalyzed, Regio- and Enantioselective N-Allylation of Indoles” Angew. Chem. Int. Ed. 2009, 48, 7841-7844. DOI: 10.1002/anie.200904338
15. Pouy, M. J.; Stanley, L. M.; Hartwig, J. F. “Enantioselective, Iridium-Catalyzed Monoallylation of Ammonia” J. Am. Chem. Soc. 2009, 131, 11312-11313. DOI: 10.1021/ja905059r
14. Stanley, L. M.; Hartwig, J. F. “Regio- and Enantioselective N-Allylations of Imidazole, Benzimidazole, and Purine Heterocycles Catalyzed by Single-Component Metallacyclic Iridium Complexes” J. Am. Chem. Soc. 2009, 131, 8971-8983. DOI: 10.1021/ja902243s
13. Sibi, M. P.; Cruz, Jr., W.; Stanley, L. M. “Enantioselective Diels-Alder Cycloadditions with beta-Substituted Pyrazolidinone Propiolimides” Synlett. 2010, 889-892. DOI: 10.1055/s-0029-1219538
12. Sibi, M. P.; Kawashima, K.; Stanley, L. M. “Diels-Alder Cycloaddition Strategy for Kinetic Resolution of Chiral Pyrazolidinones” Org. Lett. 2009, 11, 3894. DOI: 10.1021/ol901504p
11. Sibi, M. P.; Coulomb, J.; Stanley, L. M. “Enantioselective Enolate Protonations: Friedel-Crafts Reactions with alpha-Substituted Acrylates” Angew. Chem. Int. Ed. 2008, 47, 9913-9915. DOI: 10.1002/anie.200804221
10. Sibi, M. P.; Nie, X.; Shackleford, J. P.; Stanley, L. M.; Bouret, F. “Exo- and Enantioselective Diels-Alder Reactions: Pyrazolidinone Auxiliaries as a Means to Enhanced Exo Selectivity” Synlett. 2008, 2655-2658. DOI: 10.1055/s-0028-1083438
9. Sibi, M. P.; Rane, D.; Stanley, L. M.; Soeta, T. “Copper(II)-Catalyzed Exo and Enantioselective Cycloadditions of Azomethine Imines” Org. Lett. 2008, 10, 2971-2974. DOI: 10.1021/ol800904t
8. Stanley, L. M.; Sibi, M. P. “Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions” Chem. Rev. 2008, 108, 2887-2902. DOI: 10.1021/cr078371m
7. Sibi, M. P.; Stanley, L. M.; Soeta, T. “Enantioselective 1,3-Dipolar Cycloadditions of Diazoacetates with Electron-Deficient Olefins” Org. Lett. 2007, 9, 1553-1556. DOI: 10.1021/ol070364x
6. Sibi, M. P.; Chen, J.; Stanley, L. “Enantioselective Diels-Alder Reactions. Effect of the Achiral Template on Reactivity and Selectivity” Synlett. 2007, 298-302. DOI: 10.1055/s-2007-968014
5. Sibi, M. P.; Stanley, L. M.; Nie, X.; Venkatraman, L; Liu, M.; Jasperse, C. P. “The Role of Achiral Pyrazolidinone Templates in Enantioselective Diels-Alder Reactions: Scope, Limitations, and Conformational Insights” J. Am. Chem. Soc. 2007, 129, 395-405. DOI: 10.1021/ja066425o
4. Sibi, M. P.; Stanley, L. M.; Soeta, T. “Enantioselective 1,3-Dipolar Cycloaddition of Nitrile Imines to alpha-Substituted and alpha,beta-Disubstituted, alpha,beta-Unsaturated Carbonyl Substrates: A Method for Synthesizing Dihydropyrazoles Bearing a Chiral Quaternary Center” Adv. Synth. Catal. 2006, 348, 2371-2375. DOI: 10.1002/adsc.200600307
3. Stanley, L. M.; Sibi, M. P. “5,5-Dimethyl-1-(phenylmethyl)-3-pyrazolidinone” Encyclopedia of Reagents for Organic Synthesis (e-EROS) 2006. DOI: 10.1002/047084289X.rn00644
2. Sibi, M. P.; Stanley, L. M.; Jasperse, C. P. “An Entry to a Chiral Dihydropyrazole Scaffold: Enantioselective [3+2] Cycloaddition of Nitrile Imines” J. Am. Chem. Soc. 2005, 127, 8276-8277. DOI: 10.1021/ja051650b
• For a highlight see: Burgess, K. Chemistry and Industry 2005, 19 September 2005 - Issue No 18, 32.
• For a highlight see: Letters in Organic Chemistry 2006, 3 78-81.
1. Sibi, M. P.; Stanley, L. M. “Enantioselective Diethylzinc Additions to Aldehydes Catalyzed by Chiral Relay Ligands” Tetrahedron: Asymmetry 2004, 15, 335-3356. DOI: 10.1016/j.tetasy.2004.09.006
Book Chapters, Book Contributions, and Review Articles
6. Stanley, L. M.; Sibi, M. P. “Chiral Bisoxazoline Ligands” In Privileged Chiral Ligands and Catalysts; Zhou, Q.-L., Ed.; Wiley-VCH, Weinheim, Germany, 2011, pp. 171-220.
5. Hartwig, J. F.; Stanley, L. M. “Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution” Acc. Chem. Res. 2010, 43, 1461-1475.
4. Stanley, L. M.; Hartwig, J. F. “Copper-Catalyzed Allylic Substitution” In Organotransition Metal Chemistry: From Bonding to Catalysis; Hartwig, J. F., Ed.; University Science Books, Sausalito, CA, 2010, pp. 999-1008.
3. Stanley, L. M.; Sibi, M. P. “Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions” Chem. Rev. 2008, 108, 2887-2902.
2. Stanley, L. M.; Sibi, M. P. “Cu(I) and Cu(II) Lewis Acids” In Acid Catalysis in Modern Organic Synthesis; Yammamoto, H.; Ishihara, K., Eds.; Wiley-VCH, Weinheim, 2008, Vol. 2, pp. 903-985.
1. Stanley, L. M.; Sibi, M. P. “5,5-Dimethyl-1-(phenylmethyl)-3-pyrazolidinone” Encyclopedia of Reagents for Organic Synthesis (e-EROS) 2006.
